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The roles of the structure and basic sites of sodium titanates on transesterification reactions to obtain biodiesel
Josue Jonathan Machorro Lopez
ANA LILIA DE JESUS LAZARO
Fabricio Espejel Ayala
EDUARDO DE JESUS COUTIÑO GONZALEZ
JUAN CARLOS CHAVARRIA HERNANDEZ
Luis Arturo Godinez Mora Tovar
FRANCISCO JAVIER RODRIGUEZ VALADEZ
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.3390/catal9120989
SODIUM TITANATES
HETEROGENEOUS CATALYSIS
BIODIESEL
Sodium titanates were evaluated as heterogeneous catalysts for biodiesel production. Materials were prepared using an experimental design considering NaOH and TiO2 concentrations and hydrothermal and calcination temperatures as input variables. Materials characterization was carried out by DRX-Rietveld refinement, CO2-TPD, and XPS. Statistical analysis of the experimental results indicates that the calcination temperature is the most influential factor in the formation of sodium titanates with high catalytic performance in transesterification reactions. Further analysis of the oil-to-biodiesel conversion revealed that the catalytic activity of sodium titanates is directly correlated to the catalyst associated species and to the density of medium-strong basic sites on the surface of the material, obtaining up to 95% conversion to biodiesel at 60 °C using 3.6% weight catalyst with respect to oil.
2019
Artículo
Catalysts, 9(12), 989, 2019.
Inglés
Machorro, J. J., Lazaro, A. L., Espejel-Ayala, F., Coutiño-Gonzalez, E., Chavarria-Hernandez, J. C., Godínez, L., & Rodríguez-Valadez, F. J. (2019). The Roles of the Structure and Basic Sites of Sodium Titanates on Transesterification Reactions to Obtain Biodiesel. Catalysts, 9(12), 989.
ENERGÍA
Versión publicada
publishedVersion - Versión publicada
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