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The roles of the structure and basic sites of sodium titanates on transesterification reactions to obtain biodiesel | |
Josue Jonathan Machorro Lopez ANA LILIA DE JESUS LAZARO Fabricio Espejel Ayala EDUARDO DE JESUS COUTIÑO GONZALEZ JUAN CARLOS CHAVARRIA HERNANDEZ Luis Arturo Godinez Mora Tovar FRANCISCO JAVIER RODRIGUEZ VALADEZ | |
Acceso Abierto | |
Atribución-NoComercial-SinDerivadas | |
https://doi.org/10.3390/catal9120989 | |
SODIUM TITANATES HETEROGENEOUS CATALYSIS BIODIESEL | |
Sodium titanates were evaluated as heterogeneous catalysts for biodiesel production. Materials were prepared using an experimental design considering NaOH and TiO2 concentrations and hydrothermal and calcination temperatures as input variables. Materials characterization was carried out by DRX-Rietveld refinement, CO2-TPD, and XPS. Statistical analysis of the experimental results indicates that the calcination temperature is the most influential factor in the formation of sodium titanates with high catalytic performance in transesterification reactions. Further analysis of the oil-to-biodiesel conversion revealed that the catalytic activity of sodium titanates is directly correlated to the catalyst associated species and to the density of medium-strong basic sites on the surface of the material, obtaining up to 95% conversion to biodiesel at 60 °C using 3.6% weight catalyst with respect to oil. | |
2019 | |
Artículo | |
Catalysts, 9(12), 989, 2019. | |
Inglés | |
Machorro, J. J., Lazaro, A. L., Espejel-Ayala, F., Coutiño-Gonzalez, E., Chavarria-Hernandez, J. C., Godínez, L., & Rodríguez-Valadez, F. J. (2019). The Roles of the Structure and Basic Sites of Sodium Titanates on Transesterification Reactions to Obtain Biodiesel. Catalysts, 9(12), 989. | |
ENERGÍA | |
Versión publicada | |
publishedVersion - Versión publicada | |
Aparece en las colecciones: | Artículos de Investigación Arbitrados |
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