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http://cicy.repositorioinstitucional.mx/jspui/handle/1003/2107| Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide | |
| Hector Aguilar-Bolados Mehrdad Yazdani_Pedram Eduardo Quinteros Jara Quimberly Cuenca Bracamonte RAUL QUIJADA Javier Carretero González FRANCIS AVILES CETINA Miguel Lopez-Manchado Raquel Verdejo | |
| Acceso Abierto | |
| Atribución-NoComercial-SinDerivadas | |
| https://doi.org/10.1016/j.polymertesting.2020.106986 | |
| POLYMER BRUSHES MULTI-LAYER GRAPHENE OXIDE SURFACE-INITIATED CONTROLLED RADICAL POLYMERIZATION ARGET-ATRP SUSTAINABLE RESOURCES | |
| This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMI-g-GO presents outstanding properties, such as a high electrical conductivity (5.04 S m-1), low number of stacked graphene layers (6) and IG/I2D ratio of 2.05 estimated from Raman spectrum, which indicates the high quality of PMMI-g-GO as a graphenic material. In addition, polymer brushes based on PMMI represent a new green alternative for the development of polymer composite materials, since the monomer used for their production is obtained from a renewable source. Interestingly, the PMMI-g-GO nanomaterial is also capable of storing Li+ ions without the need of using electron conductive additives that are usually employed in the electrode's composition of conventional lithium ion batteries. This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMI-g-GO presents outstanding properties, such as a high electrical conductivity (5.04 S m-1), low number of stacked graphene layers (6) and IG/I2D ratio of 2.05 estimated from Raman spectrum, which indicates the high quality of PMMI-g-GO as a graphenic material. In addition, polymer brushes based on PMMI represent a new green alternative for the development of polymer composite materials, since the monomer used for their production is obtained from a renewable source. Interestingly, the PMMI-g-GO nanomaterial is also capable of storing Li+ ions without the need of using electron conductive additives that are usually employed in the electrode's composition of conventional lithium ion batteries. | |
| 2021 | |
| Artículo | |
| Polymer Testing, 93, 106986, 2021. | |
| Inglés | |
| Aguilar-Bolados, H., Yazdani-Pedram, M., Quinteros-Jara, E., Cuenca-Bracamonte, Q., Quijada, R., Carretero-González, J., ... & Verdejo, R. (2021). Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide. Polymer Testing, 93, 106986. | |
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| Versión publicada | |
| publishedVersion - Versión publicada | |
| Aparece en las colecciones: | Artículos de Investigación Arbitrados |
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