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Photochemical transformations of chalcone-vitamin E hybrids
JIMMY JOSUE CEBALLOS CRUZ
Jean-Jacques HELESBEUX
Guillaume VIAULT
DENIS SERAPHIN
GUMERSINDO MIRON LOPEZ
Ruben M Carballo
Pascal Richomme
Luis Manuel Peña Rodríguez
Acceso Abierto
Atribución-NoComercial-SinDerivadas
http://dx.doi.org/10.29356/jmcs.v66i1.1670
PHOTOISOMERIZATION
SUBSTITUENT EFFECTS
SOLVENT EFFECTS
AGGREGATION
DEOXYANTHOCYANIDIN
Chalcone-vitamin E hybrids 6’-O-tosyl-3,4,5-trimethoxy-δ-tocopherol-chalcone (1), 3,4,5-trimethoxy-δ-tocopherol-chalcone (2), 6’-O-tosyl-3,4,5-trimethoxy-δ-tocopherol-retrochalcone (3) and 3,4,5-trimethoxy-δ-tocopherol-retrochalcone (4) were synthesized as part of a search for new biological activities in these types of derivatives. We report herein on the photoisomerization products of hybrids 1-4, and the effects of the solvent and substitution patterns in producing secondary products such as flavanone 6, 3-deoxyanthocyanidin 8, and hemiketal 10. Photochemically-induced changes are considered important since structural modifications and/or the presence of additional products can affect the biological activity of this type of semisynthetic hybrids. © 2022, Sociedad Química de México.
2022
Artículo
Journal of the Mexican Chemical Society, 66(1), 120-129, 2022.
Inglés
Ceballos-Cruz, J. J., Hélesbeux, J. J., Viault, G., Séraphin, D., Mirón-Lopez, G., Carballo, R. M., ... & Peña-Rodríguez, L. M. (2022). Photochemical transformations of chalcone-vitamin e hybrids. Journal of the Mexican Chemical Society, 66(1), 120-129.
BIOLOGÍA MOLECULAR
Versión publicada
publishedVersion - Versión publicada
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