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Photochemical transformations of chalcone-vitamin E hybrids | |
JIMMY JOSUE CEBALLOS CRUZ Jean-Jacques HELESBEUX Guillaume VIAULT DENIS SERAPHIN GUMERSINDO MIRON LOPEZ Ruben M Carballo Pascal Richomme Luis Manuel Peña Rodríguez | |
Acceso Abierto | |
Atribución-NoComercial-SinDerivadas | |
http://dx.doi.org/10.29356/jmcs.v66i1.1670 | |
PHOTOISOMERIZATION SUBSTITUENT EFFECTS SOLVENT EFFECTS AGGREGATION DEOXYANTHOCYANIDIN | |
Chalcone-vitamin E hybrids 6’-O-tosyl-3,4,5-trimethoxy-δ-tocopherol-chalcone (1), 3,4,5-trimethoxy-δ-tocopherol-chalcone (2), 6’-O-tosyl-3,4,5-trimethoxy-δ-tocopherol-retrochalcone (3) and 3,4,5-trimethoxy-δ-tocopherol-retrochalcone (4) were synthesized as part of a search for new biological activities in these types of derivatives. We report herein on the photoisomerization products of hybrids 1-4, and the effects of the solvent and substitution patterns in producing secondary products such as flavanone 6, 3-deoxyanthocyanidin 8, and hemiketal 10. Photochemically-induced changes are considered important since structural modifications and/or the presence of additional products can affect the biological activity of this type of semisynthetic hybrids. © 2022, Sociedad Química de México. | |
2022 | |
Artículo | |
Journal of the Mexican Chemical Society, 66(1), 120-129, 2022. | |
Inglés | |
Ceballos-Cruz, J. J., Hélesbeux, J. J., Viault, G., Séraphin, D., Mirón-Lopez, G., Carballo, R. M., ... & Peña-Rodríguez, L. M. (2022). Photochemical transformations of chalcone-vitamin e hybrids. Journal of the Mexican Chemical Society, 66(1), 120-129. | |
BIOLOGÍA MOLECULAR | |
Versión publicada | |
publishedVersion - Versión publicada | |
Aparece en las colecciones: | Artículos de Investigación Arbitrados |
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