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http://cicy.repositorioinstitucional.mx/jspui/handle/1003/3067| Assessing the effect of cellulose nanocrystal content on the biodegradation kinetics of multiscale polylactic acid composites under controlled thermophilic composting conditions | |
| Priscila Esther Colli Góngora NORA MAGALLY MOO TUN Pedro Jesús Herrera Franco Alex Valadez González | |
| Acceso Abierto | |
| Atribución-NoComercial-SinDerivadas | |
| https://doi.org/10.3390/polym15143093 | |
| MULTISCALE BIOCOMPOSITES PLA CELLULOSE NANOCRYSTALS CELLULOSE MICROFIBERS BIODEGRADATION KINETICS CONTROLLED COMPOSTING | |
| This work studied the effect of cellulose nanocrystal (NCC) content on the biodegradation kinetics of PLA-based multiscale cellulosic biocomposites (PLAMCBs). To facilitate biodegradation, the materials were subjected to thermo-oxidation before composting. Biodegradation was carried out for 180 days under controlled thermophilic composting conditions according to the ASTM D 5338 standard. A first-order model based on Monod’s kinetics under limiting substrate conditions was used to study the effect of cellulose nanocrystal (NCC) content on the biodegradation kinetics of multiscale composite materials. It was found that thermo-oxidation at 70 °C for 160 h increased the biodegradability of PLA. Also, it was found that the incorporation of cellulosic fibrous reinforcements increased the biodegradability of PLA by promoting hydrolysis during the first stage of composting. Likewise, it was found that partial substitution of micro cellulose (MFC) by cellulose nanocrystals (NCCs) increased the biodegradability of the biocomposite. This increase was more evident as the NCC content increased, which was attributed to the fact that the incorporation of cellulose nanocrystals facilitated the entry of water into the material and therefore promoted the hydrolytic degradation of the most recalcitrant fraction of PLA from the bulk and not only by surface erosion. | |
| 2023 | |
| Artículo | |
| Polymers 2023, 15, 3093, 2023 | |
| Inglés | |
| Colli-Gongora, P.E.; Moo-Tun, N.M.; Herrera-Franco, P.J.; Valadez-Gonzalez, A. Assessing the effect of cellulose nanocrystal content on the biodegradation kinetics of multiscale polylactic acid composites under controlled thermophilic composting conditions. Polymers 2023, 15, 3093. https://doi.org/10.3390/polym15143093 | |
| PROPIEDADES DE LOS MATERIALES | |
| Versión publicada | |
| publishedVersion - Versión publicada | |
| Aparece en las colecciones: | Artículos de Investigación Arbitrados |
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| 2023_Priscila_Colli.pdf | 3.18 MB | Adobe PDF | Visualizar/Abrir |