Por favor, use este identificador para citar o enlazar este ítem: http://cicy.repositorioinstitucional.mx/jspui/handle/1003/3132
Pulcaffeate, a Trimeric Caffeic Acid derivative from Bourreria pulchra
GILDA JOSEFINA EROSA REJON
Jesús Alejandro Yam Puc
Luis Manuel Peña Rodríguez
Olov Sterner
Acceso Abierto
Atribución-NoComercial-SinDerivadas
https://doi.org/10.29356/jmcs.v67i3.1985
BORAGINACEAE
CINNAMIC ACID
CAFFEIC ACID
INTRAMOLECULAR CYCLOADDITION
DIELS-ALDER REACTION
The trimeric caffeic acid derivative pulcaffeate (1) was isolated from the organic crude extract of the roots of Bourreria pulchra(Boraginaceae). The biosynthesis of 1 appears to involve an intramolecular Diels-Alder reaction between a cyclohexa-1,3-diene intermediate, generated by the oxidation of the aromatic ring of a cinnamic acid unit, and the conjugated double bond of a caffeic acid unit. The structure of the new metabolite was elucidated through a detailed analysis of its 1H and 13C NMR spectroscopic data. This is the first report of a trimeric metabolite occurring in B. pulchra.
2023
Artículo
Journal of the Mexican Chemical Society, 67(3), 182-186, 2023.
Inglés
Erosa-Rejón, G. J., Yam-Puc, A., Peña-Rodríguez, L. M., & Sterner, O. (2023). Pulcaffeate, a Trimeric Caffeic Acid Derivative from Bourreria pulchra. Journal of the Mexican Chemical Society, 67(3), 182-186.
BIOLOGÍA MOLECULAR
Versión publicada
publishedVersion - Versión publicada
Aparece en las colecciones: Artículos de Investigación Arbitrados

Cargar archivos:


Fichero Tamaño Formato  
2023_Gilda_Erosa.pdf309.59 kBAdobe PDFVisualizar/Abrir