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Pulcaffeate, a Trimeric Caffeic Acid derivative from Bourreria pulchra | |
GILDA JOSEFINA EROSA REJON Jesús Alejandro Yam Puc Luis Manuel Peña Rodríguez Olov Sterner | |
Acceso Abierto | |
Atribución-NoComercial-SinDerivadas | |
https://doi.org/10.29356/jmcs.v67i3.1985 | |
BORAGINACEAE CINNAMIC ACID CAFFEIC ACID INTRAMOLECULAR CYCLOADDITION DIELS-ALDER REACTION | |
The trimeric caffeic acid derivative pulcaffeate (1) was isolated from the organic crude extract of the roots of Bourreria pulchra(Boraginaceae). The biosynthesis of 1 appears to involve an intramolecular Diels-Alder reaction between a cyclohexa-1,3-diene intermediate, generated by the oxidation of the aromatic ring of a cinnamic acid unit, and the conjugated double bond of a caffeic acid unit. The structure of the new metabolite was elucidated through a detailed analysis of its 1H and 13C NMR spectroscopic data. This is the first report of a trimeric metabolite occurring in B. pulchra. | |
2023 | |
Artículo | |
Journal of the Mexican Chemical Society, 67(3), 182-186, 2023. | |
Inglés | |
Erosa-Rejón, G. J., Yam-Puc, A., Peña-Rodríguez, L. M., & Sterner, O. (2023). Pulcaffeate, a Trimeric Caffeic Acid Derivative from Bourreria pulchra. Journal of the Mexican Chemical Society, 67(3), 182-186. | |
BIOLOGÍA MOLECULAR | |
Versión publicada | |
publishedVersion - Versión publicada | |
Aparece en las colecciones: | Artículos de Investigación Arbitrados |
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