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Chemical synthesis and electrochemical performance of Hausmannite Mn3O4/rGO composites for supercapacitor applications
LORENA GUADALUPE CUELLAR HERRERA
ELSA MIRIAM ARCE ESTRADA
Daniella Esperanza Pacheco Catalán
Leonardo Vivas
JOSE ORTIZ LANDEROS
JUAN CANCIO JIMENEZ LUGOS
JOSE ANTONIO ROMERO SERRANO
Acceso Abierto
Atribución-NoComercial-SinDerivadas
10.1016/j.ijoes.2024.100737
Mn3O4
MECHANOCHEMICAL SYNTHESIS
REDUCED GRAPHENE OXIDE
SUPERCAPACITORS
A simple approach for the preparation of hausmannite Mn3O4/rGO composites for supercapacitor electrodes is reported. The individual Mn3O4 and rGO phases were synthesized by dry ball milling and the modified Hummers method, respectively. Subsequently, composites with different Mn3O4/rGO ratios were prepared by ultrasonic treatment. The physicochemical and electrochemical properties were characterized. In addition, the electrochemical performance of an electrode supercapacitor was tested in two different configurations: a three-electrode cell and a symmetric supercapacitor (SSC). The three-electrode cell showed an excellent specific capacitance of 525 F·g[sbnd]1 at 5 mV·s[sbnd]1. To investigate practical applications, Mn3O4/rGO were used as electrodes to construct symmetric supercapacitors. The composite with a volume ratio of Mn3O4:rGO of 7:3 showed a remarkable stability of 85 % after 5000 charge-discharge cycles. This SSC also delivered an energy density of 6.25 W·h·kg−1 at a power density of 125 W·h·kg−1 with a current density of 0.5 A·g−1, and 5.36 W·h·kg−1 at a power density of 500 W·h·kg−1 and 2 A·g−1. © 2024 The Authors
2024
Artículo
International Journal of Electrochemical Science, 19(9), 100737, 2024.
Inglés
ENERGÍA
Versión publicada
publishedVersion - Versión publicada
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